TY - CONF AU - Howard, K. AU - Bafia, D. AU - Grassellino, A. AU - Kim, Y.K. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - The Collaborative Effects of Intrinsic and Extrinsic Impurities in Low RRR SRF Cavities J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - The SRF community has shown that introducing certain impurities into high-purity niobium can improve quality factors and accelerating gradients. We question why some impurities improve RF performance while others hinder it. The purpose of this study is to characterize the impurity profile of niobium coupons with a low residual resistance ratio (RRR) and correlate these impurities with the RF performance of low RRR cavities so that the mechanism of impurity-based improvements can be better understood and improved upon. The combination of RF testing and material analysis reveals a microscopic picture of why low RRR cavities experience low BCS resistance behavior more prominently than their high RRR counterparts. We performed surface treatments, low temperature baking and nitrogen-doping, on low RRR cavities to evaluate how the intentional addition of oxygen and nitrogen to the RF layer further improves performance through changes in the mean free path and impurity profile. The results of this study have the potential to unlock a new understanding on SRF materials and enable the next generation of high Q/high gradient surface treatments. PB - JACoW Publishing CP - Geneva, Switzerland SP - 162 EP - 166 KW - cavity KW - SRF KW - niobium KW - radio-frequency KW - accelerating-gradient DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB032 UR - https://jacow.org/srf2023/papers/mopmb032.pdf ER - TY - CONF AU - Howard, K. AU - Bafia, D. AU - Grassellino, A. AU - Kim, Y.K. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Exploration of Parameters that Affect High Field Q-Slope J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - The onset of high field Q-slope (HFQS) around 25 MV/m prevents cavities in electropolished (EP) condition from reaching high quality factors at high gradients due to the precipitation of niobium hydrides during cooldown. These hydrides are non-superconducting at 2 K, and contribute to losses such as Q disease and HFQS. We are interested in exploring the parameters that affect the behavior of HFQS. We study a high RRR cavity that received an 800 C by 3 hour bake and EP treatment to observe HFQS. First, we explore the effect of trapped magnetic flux. The cavity is tested after cooling slowly through Tc while applying various levels of ambient field. We observe the onset of the HFQS and correlate this behavior with the amount of trapped flux. Next, we investigate the effect of the size/concentration of hydrides. The cavity is tested after holding the temperature at 100 K for 12 hours during the cooldown to promote the growth of hydrides. We can correlate the behavior of the HFQS with the increased hydride concentration. Our results will help further the understanding of the mechanism of HFQS. PB - JACoW Publishing CP - Geneva, Switzerland SP - 178 EP - 182 KW - cavity KW - niobium KW - accelerating-gradient KW - SRF KW - radio-frequency DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB037 UR - https://jacow.org/srf2023/papers/mopmb037.pdf ER - TY - CONF AU - Hu, H. AU - Bafia, D. AU - Kim, Y.K. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Comparing the Effectiveness of Low Temperature Bake in EP and BCP Cavities J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Electropolishing (EP) and buffered chemical polishing (BCP) are conventional surface preparation techniques for superconducting radiofrequency (SRF) cavities. Both EP and BCP treated SRF cavities display high field Q-slope (HFQS) which degrades performance at high gradients. While high gradient performance in EP cavities can be improved by introducing oxygen via a low temperature bake (LTB) of 120^{°}C by 48 hours, LTB does not consistently remove HFQS in BCP cavities. There is no consensus as to why LTB is not effective on BCP prepared cavities. We examine quench in EP, BCP, EP+LTB, and BCP+LTB treated 1.3 GHz single-cell Nb cavities by studying the heating behavior with field using a temperature mapping system. Cavity performance is correlated to characterizations of surface impurity profile obtained via time of flight secondary ion mass spectrometry studies. We observe a difference in near surface hydrogen concentration following BCP compared to EP that may suggest that the causes of quench in EP and BCP cavities are different. PB - JACoW Publishing CP - Geneva, Switzerland SP - 187 EP - 190 KW - cavity KW - SRF KW - niobium KW - radio-frequency KW - factory DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB040 UR - https://jacow.org/srf2023/papers/mopmb040.pdf ER -