TY - CONF AU - Gaitan, G. AU - Holic, A.T. AU - Howes, W.I. AU - Kulina, G. AU - Liepe, M. AU - Quigley, P. AU - Sears, J. AU - Sun, Z. AU - Wendland, B.W. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Development of a Plasma-Enhanced Chemical Vapor Deposition System for High-Performance SRF Cavities J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Next-generation, thin-film surfaces employing Nb₃Sn, NbN, NbTiN, or other compound superconductors are essential for reaching enhanced RF performance levels in SRF cavities. However, optimized, advanced deposition processes are required to enable high-quality films of such materials on large and complex-shaped cavities. For this purpose, Cornell University is developing a plasma-enhanced chemical vapor deposition (CVD) system that facilitates coating on complicated geometries with a high deposition rate. This system is based on a high-temperature tube furnace with a high-vacuum, gas, and precursor delivery system, and uses plasma to significantly reduce the required processing temperature and promote precursor decomposition. Here we present an update on the development of this system, including final system design, safety considerations, assembly, and commissioning. PB - JACoW Publishing CP - Geneva, Switzerland SP - 100 EP - 103 KW - cavity KW - SRF KW - plasma KW - vacuum KW - controls DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB015 UR - https://jacow.org/srf2023/papers/mopmb015.pdf ER - TY - CONF AU - Sitaraman, N. AU - Arias, T. AU - Harbick, A.V. AU - Liepe, M. AU - Transtrum, M.K. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - A Comprehensive Picture of Hydride Formation and Dissipation J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Research linking surface hydrides to Q-disease, and the subsequent development of methods to eliminate surface hydrides, is one of the great successes of SRF cavity R\&D. We use time-dependent Ginzburg-Landau to extend the theory of hydride dissipation to sub-surface hydrides. Just as surface hydrides cause Q-disease behavior, we show that sub-surface hydrides cause high-field Q-slope (HFQS) behavior. We find that the abrupt onset of HFQS is due to a transition from a vortex-free state to a vortex-penetration state. We show that controlling hydride size and depth through impurity doping can eliminate HFQS. PB - JACoW Publishing CP - Geneva, Switzerland SP - 119 EP - 123 KW - cavity KW - site KW - superconductivity KW - SRF KW - niobium DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB020 UR - https://jacow.org/srf2023/papers/mopmb020.pdf ER - TY - CONF AU - Méndez, C.A. AU - Arias, T. AU - Liepe, M. AU - Sitaraman, N. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Theoretical Study of Thin Noble-Metal Films on the Niobium Surface J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Recent experiments suggest that noble-metal deposition on niobium metal surfaces can remove the surface oxide and ultimately improve superconducting radio-frequency (SRF) cavities performance. In this preliminary study, we use density-functional theory to investigate the potential for noble-metal passivation of realistic, polycrystalline niobium surfaces for SRF. Specifically, we investigate the stability of gold and palladium monolayers on niobium surfaces with different crystal orientations and evaluate the impact of these impurities on superconducting properties. In particular, our results suggest that gold can grow in thin layers on the niobium surface, whereas palladium rather tends to dissolve into the niobium cavity. These results will help inform ongoing experimental efforts to passivate niobium surfaces of SRF cavities. PB - JACoW Publishing CP - Geneva, Switzerland SP - 230 EP - 233 KW - niobium KW - interface KW - lattice KW - electron KW - experiment DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB053 UR - https://jacow.org/srf2023/papers/mopmb053.pdf ER - TY - CONF AU - Seddon-Stettler, S.G. AU - Liepe, M. AU - Oseroff, T.E. AU - Sitaraman, N. AU - Sun, Z. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Surface Characterization Studies of Gold-Plated Niobium J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - The native niobium oxide layer present on niobium has been shown to affect the performace of superconducting RF cavities. Extremely thin layers of gold on the surface of niobium have the potential to suppress surface oxidation and improve cavity performance. However, depositing uniform layers of gold at the desired thickness (sub-nm) is difficult, and different deposition methods may have different effects on the gold surface, on the niobium surface, and on the interface between the two. In particular, the question of whether gold deposition actually passivates the niobium oxide is extremely relevant for assessing the potential of gold deposition to improve RF performance. This work builds on previous research studying the RF performance of gold/niobium bilayers with different gold layer thicknesses. We here consider alternative methods to characterize the composition and chemical properties of gold/niobium bilayers to supplement the previous RF study. PB - JACoW Publishing CP - Geneva, Switzerland SP - 290 EP - 292 KW - niobium KW - cavity KW - controls KW - site KW - radio-frequency DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB076 UR - https://jacow.org/srf2023/papers/mopmb076.pdf ER - TY - CONF AU - Arnold, S.G. AU - Arias, T. AU - Gaitan, G. AU - Liepe, M. AU - Shpani, L. AU - Sitaraman, N. AU - Sun, Z. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Optimizing Growth of Niobium-3 Tin Through Pre-nucleation Chemical Treatments J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Nb₃Sn is a promising alternative material for SRF cavities that is close to reaching practical applications. To date, one of the most effective growth methods for this material is vapor diffusion, yet further improvement is needed for Nb₃Sn to reach its full potential. The major issues faced by vapor diffusion are tin depleted regions and surface roughness, both of which lead to impaired performance. Literature has shown that the niobium surface oxide plays an important role in the binding of tin to niobium. In this study, we performed various chemical treatments on niobium samples pre-nucleation to enhance tin nucleation. We quantify the effect that these various treatments had through scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). These methods reveal information on tin nucleation density and uniformity, and a thin tin film present on most samples, even in the absence of nucleation sites. We present our findings from these surface characterization methods and introduce a framework for quantitatively comparing the samples. We plan to apply the most effective treatment to a cavity and conduct an RF test soon. PB - JACoW Publishing CP - Geneva, Switzerland SP - 337 EP - 341 KW - site KW - niobium KW - cavity KW - SRF KW - controls DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-MOPMB093 UR - https://jacow.org/srf2023/papers/mopmb093.pdf ER - TY - CONF AU - Kelley, M.M. AU - Arias, T. AU - Deyo, S. AU - Liarte, D. AU - Liepe, M. AU - Oseroff, T.E. AU - Sethna, J.P. AU - Sitaraman, N. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - A Three-Fluid Model of Dissipation at Surfaces in Superconducting Radiofrequency Cavities J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Experiments on superconducting cavities have found that under large RF fields the quality factor can improve with increasing field amplitude, a so-called anti-Q slope. We numerically solve the Bogoliubov-de Gennes equations at a superconducting surface in a parallel magnetic field, finding at large fields there are surface quasiparticle states with energies below the bulk superconducting gap that emerge and disappear as the field cycles. Modifying the standard two-fluid model, we introduce a ‘‘three’’-fluid model where we partition the normal fluid to consider continuum and surface quasiparticle states separately. We compute dissipation in a semi-classical theory of conductivity, where we provide physical estimates of elastic scattering times of Bogoliubov quasiparticles with point-like impurities having potential strengths informed from complementary ab initio calculations of impurities in bulk niobium. We show, in this simple yet effective framework, how the relative scattering rates of surface and continuum quasiparticle states can play a role in producing an anti-Q slope while demonstrating how this model naturally includes a mechanism for turning the anti-Q slope on and off. PB - JACoW Publishing CP - Geneva, Switzerland SP - 361 EP - 368 KW - scattering KW - cavity KW - electron KW - niobium KW - SRF DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-TUIBA01 UR - https://jacow.org/srf2023/papers/tuiba01.pdf ER - TY - CONF AU - Sitaraman, N. AU - Arias, T. AU - Baraissov, Z. AU - Gaitan, G. AU - Liepe, M. AU - Muller, D.A. AU - Oseroff, T.E. AU - Sun, Z. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Progress on Zirconium-Doped Niobium Surfaces J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - The first experimental studies of zirconium-doped surfaces verified that zirconium can enhance the critical temperature of the surface, resulting in a lower BCS resistance than standard-recipe niobium. However, they also produced a disordered oxide layer, resulting in a higher residual resistance than standard-recipe niobium. Here, we show that zirconium-doped surfaces can grow well-behaved thin oxide layers, with a very thin ternary suboxide capped by a passivating ZrO2 surface. The elimination of niobium pentoxide may allow zirconium-doped surfaces to achieve low residual resistance. PB - JACoW Publishing CP - Geneva, Switzerland SP - 398 EP - 400 KW - niobium KW - ECR KW - vacuum KW - electron KW - superconductivity DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-TUPTB004 UR - https://jacow.org/srf2023/papers/tuptb004.pdf ER - TY - CONF AU - Sun, Z. AU - Baraissov, Z. AU - Liepe, M. AU - Muller, D.A. AU - Oseroff, T.E. AU - Thompson, M.O. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Materials Design for Superconducting RF Cavities: Electroplating Sn, Zr, and Au onto Nb and and Chemical Vapor Deposition J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Materials scientists seek to contribute to the development of next-generation superconducting radio-frequency (SRF) accelerating cavities. Here, we summarize our achievements and learnings in designing advanced SRF materials and surfaces, including Nb₃Sn [1¿3], ZrNb(CO) [4, 5], and Au/Nb surface design [6,7]. Our efforts involve electrochemical synthesis, phase transformation, and surface chemistry, which are closely coupled with superconducting properties, SRF performance, and engineering considerations. We develop electrochemical processes for Sn, Zr, and Au on the Nb surface, an essential step in our investigation for producing high-quality Nb₃Sn, ZrNb(CO), and Au/Nb structures. Additionally, we design a custom chemical vapor deposition system to offer additional growth options. Notably, we find the second-phase NbC formation in ZrNb(CO) and in ultra-high-vacuum baked or nitrogen-processed Nb. We also identify low-dielectric-loss ZrO2 on Nb and NbZr(CO) surfaces. These advancements provide materials science approaches dealing with fundamental and technical challenges to build high-performance, multi-scale, robust SRF cavities for particle accelerators and quantum applications. PB - JACoW Publishing CP - Geneva, Switzerland SP - 401 EP - 404 KW - cavity KW - SRF KW - plasma KW - controls KW - niobium DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-TUPTB006 UR - https://jacow.org/srf2023/papers/tuptb006.pdf ER - TY - CONF AU - Shpani, L. AU - Arnold, S.G. AU - Gaitan, G. AU - Liepe, M. AU - Oseroff, T.E. AU - Porter, R.D. AU - Sitaraman, N. AU - Stilin, N.A. AU - Sun, Z. AU - Verboncoeur, N.M. ED - Saito, Kenji ED - Xu, Ting ED - Sakamoto, Naruhiko ED - Schaa, Volker R.W. ED - Thomas, Paul W. TI - Development of High-performance Niobium-3 Tin Cavities at Cornell University J2 - Proc. of SRF2023, Grand Rapids, MI, USA, 25-30 June 2023 CY - Grand Rapids, MI, USA T2 - International Conference on RF Superconductivity T3 - 21 LA - english AB - Niobium-3 tin is a promising material for next-generation superconducting RF cavities due to its high critical temperature and high theoretical field limit. There is currently significant worldwide effort aiming to improve Nb₃Sn growth to push this material to its ultimate performance limits. This talk will present an overview of Nb₃Sn cavity development at Cornell University. One approach we are pursuing is to further advance the vapor diffusion process through optimized nucleation and film thickness. Additionally, we are exploring alternative Nb₃Sn growth methods, such as the development of a plasma-enhanced chemical vapor deposition (CVD) system, as well as Nb₃Sn growth via electrochemical synthesis. PB - JACoW Publishing CP - Geneva, Switzerland SP - 600 EP - 606 KW - cavity KW - niobium KW - SRF KW - site KW - accelerating-gradient DA - 2023/09 PY - 2023 SN - 2673-5504 SN - 978-3-95450-234-9 DO - doi:10.18429/JACoW-SRF2023-WEIAA04 UR - https://jacow.org/srf2023/papers/weiaa04.pdf ER -